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Quantum Superposition in Quantum Mechanics

Quantum superposition is a foundational concept in physics that challenges our everyday understanding of reality. It proposes that quantum systems can exist in multiple states simultaneously until measured or observed. This counterintuitive idea, central to modern physics, underpins much of quantum mechanics and lies at the heart of innovations like quantum computing. To grasp the implications of superposition, students must first understand the nature of atomic physics, including how quantum numbers and electron configuration govern the probabilistic behavior of particles within the structure of the atom.

The idea of a system being in a superposition of states—such as a particle being in two places at once or an electron having multiple spin orientations—is best described using the formalism of the wave function and Schrödinger’s equation. These mathematical tools predict the probabilities of different outcomes but not the definite results until observation. The principles of superposition extend to macroscopic systems, as explored in thought experiments like Schrödinger’s cat, and have implications for quantum tunneling and wave-particle duality. These effects are not just theoretical—they are experimentally verified and crucial in fields such as condensed matter physics and nuclear physics.

Quantum superposition also interacts deeply with other phenomena in particle physics, where entities like bosons and fermions exhibit behaviors that challenge classical intuition. These particles interact via the fundamental forces, and their dynamics are best described using quantum field theory. For example, in processes such as nuclear fission or nuclear fusion, particles transition between superposed states as they exchange energy and interact. Superposition is also critical in analyzing nuclear reactions and decay patterns in radioactivity and isotopes.

Furthermore, superposition ties closely to the philosophical and probabilistic debates surrounding Heisenberg’s uncertainty principle and the phenomena of quantum entanglement. These concepts suggest a reality in which outcomes are not predetermined but emerge through observation, an idea that challenges the deterministic worldview of relativity. Even within statistical mechanics, superposition alters how systems evolve under uncertainty. Aspiring physicists who master these ideas are better equipped to navigate the complexities of modern physics and engage with advanced research and technologies shaped by quantum theory.

 
A visually striking depiction of quantum superposition, illustrating a quantum particle existing in multiple states simultaneously with wavefunction overlays and probability distributions.
A visually striking depiction of quantum superposition, illustrating a quantum particle existing in multiple states simultaneously with wavefunction overlays and probability distributions.
This digital illustration represents the principle of quantum superposition, where a single quantum particle can exist in multiple states at once until measured. The central sphere symbolizes the quantum particle, while the layered and radiating waveforms surrounding it depict overlapping probability amplitudes of different possible states. The dome-like transparent boundary reinforces the idea of confinement within a potential well or observation boundary, with the surrounding grid indicating the quantum field framework. This visualization emphasizes how superposition underpins quantum computing, tunneling, and the probabilistic nature of quantum mechanics. 🎓 Looking for the computing application? See Quantum Superposition in Quantum Computing.

Table of Contents

Concept of Quantum Superposition

In classical physics, objects exist in well-defined states. For example, a ball is either on the ground or in the air; it cannot be both simultaneously. However, in quantum mechanics, particles like electrons, photons, and atoms can occupy multiple states simultaneously. This phenomenon is called superposition.

  • Mathematically, a quantum system is described by a wavefunction (ψ), which encapsulates all possible states the system can be in. If a quantum particle can exist in two distinct states, say ∣A⟩ and ∣B⟩, the superposition principle states that the system can be in a linear combination of these states:

    ∣Ψ⟩ = α∣A⟩ + β∣B⟩

    Where:

    ∣Ψ⟩ is the superposed state.
    α and β are complex probability amplitudes that determine the likelihood of the system being found in state ∣A⟩ or ∣B⟩ when measured.

    The probabilities of the system being in state ∣A⟩ or ∣B⟩ are given by ∣α∣² and ∣β∣², respectively, with the condition that ∣α∣² + ∣β∣² = 1.

Until a measurement is made, the system exists in both states simultaneously, with certain probabilities for each outcome. Upon measurement, the system “collapses” into one of these possible states.


Examples of Quantum Superposition

Electron Energy States in Atoms

Electrons in atoms are not restricted to a single energy state before measurement. Instead, they can exist in a superposition of energy levels. For example, an electron in a hydrogen atom can be in a superposition of the first and second energy levels. Only when the electron is measured does it “choose” an energy level.

Photon Polarization

Photons (particles of light) can exhibit superposition in their polarization states. A photon can be horizontally polarized (∣H⟩) or vertically polarized (∣V⟩), or it can exist in a superposition of both:

∣Ψ⟩ = (1/2)(∣H⟩ + ∣V⟩)

This principle is exploited in quantum optics and quantum communication systems.

Ψ=12(H+V)|\Psi\rangle = \frac{1}{\sqrt{2}}(|H\rangle + |V\rangle)

This principle is exploited in quantum optics and quantum communication systems.

Quantum Bits (Qubits)

In quantum computing, a qubit (quantum bit) can exist in a superposition of both the and states simultaneously:

Ψ=α0+β1

This is fundamentally different from classical bits, which can only be 0 or 1 at any given time. Superposition allows quantum computers to process vast amounts of information in parallel, making them exponentially more powerful for certain types of calculations.


Schrödinger’s Cat Thought Experiment

To illustrate the strange implications of quantum superposition on a macroscopic scale, Erwin Schrödinger proposed his famous thought experiment in 1935.

Scenario:

  • A cat is placed in a sealed box with a radioactive atom, a Geiger counter, a vial of poison, and a hammer.
  • If the atom decays (a quantum event), the Geiger counter triggers the hammer to break the vial, releasing poison and killing the cat.
  • If the atom does not decay, the cat remains alive.
  • The decay of the atom is a quantum event and is governed by superposition, meaning the atom is both decayed and undecayed until observed.

Implication:
According to the principle of superposition, the cat is simultaneously alive and dead until someone opens the box and observes the system. This paradox highlights the conflict between quantum mechanics and classical intuition, raising profound questions about when and how quantum superpositions “collapse” into definite outcomes.


Mathematical Framework of Superposition

The mathematics of superposition arises from the linearity of the Schrödinger equation, the fundamental equation of quantum mechanics:

itΨ(t)=H^Ψ(t)

Where:

∣Ψ(t)⟩ is the system’s wavefunction evolving over time.

Ĥ is the Hamiltonian operator, representing the total energy of the system.

ℏ is the reduced Planck’s constant.

Because the Schrödinger equation is linear, if ∣ψ₁⟩ and ∣ψ₂⟩ are solutions, any linear combination α∣ψ₁⟩ + β∣ψ₂⟩ is also a solution. This property directly leads to the superposition principle.


Measurement and Wavefunction Collapse

A critical feature of superposition is the concept of wavefunction collapse. While a quantum system can exist in multiple states simultaneously, the act of measurement forces the system to randomly “choose” one of these states.

  • Before Measurement: The system is in a superposed state.
  • Upon Measurement: The system collapses into one of the possible eigenstates with a probability determined by the amplitude squared |α|2

This process is inherently probabilistic, and no underlying mechanism in standard quantum mechanics explains how or why the collapse occurs—a major subject of debate in quantum foundations.

Visualization of quantum measurement and wavefunction collapse, showing a quantum state reducing from a superposition into a single outcome upon observation.
Measurement and Wavefunction Collapse: illustrating the transition from a superposed quantum state to a definite eigenstate upon observation, emphasizing the probabilistic nature of collapse.

This educational illustration portrays the process of wavefunction collapse in quantum mechanics. A particle is initially depicted in a superposition of multiple possible states, visualized through overlapping waveforms or probabilistic layers. Upon measurement, this superposition collapses into a single, well-defined outcome—an eigenstate—determined by the probability amplitude squared. The image captures the dramatic reduction of quantum uncertainty through observation, highlighting the inherently probabilistic nature of quantum measurements. This collapse is central to understanding how quantum systems transition from ambiguity to certainty during interaction with a measuring device, a phenomenon that continues to puzzle and inspire physicists.


Physical and Philosophical Implications

Challenge to Classical Reality

Superposition suggests that particles do not have definite properties until they are observed, undermining the classical notion that objects possess well-defined states independent of measurement.

Quantum Nonlocality

Superposition, when combined with entanglement, leads to the phenomenon of nonlocality, where the measurement of one particle can instantaneously affect another, regardless of distance.

Observer Effect

The fact that observation collapses the wavefunction raises questions about the role of the observer in defining reality. This leads to interpretations like the Copenhagen interpretation and the Many-Worlds interpretation.


Applications of Quantum Superposition

Quantum Computing

Superposition allows quantum computers to perform parallel computations. A qubit in superposition can represent both 0 and 1 simultaneously, enabling quantum algorithms like Shor’s algorithm for factoring and Grover’s algorithm for search.

Quantum computing illustration showing superposition, parallel processing, and quantum circuits representing qubits in simultaneous 0 and 1 states.
Quantum Computing and Superposition – Visualizing qubits performing parallel computations with applications in factoring and search algorithms.

This digital illustration captures the essence of quantum computing powered by superposition. The image depicts glowing qubits existing in both 0 and 1 states simultaneously, enabling massive parallelism. Quantum circuits, entanglement pathways, and abstract visualizations of Shor’s and Grover’s algorithms demonstrate how quantum systems process complex problems far beyond classical capabilities. This representation highlights the transformative potential of quantum computation in cryptography, optimization, and big data analytics.

 

Quantum Cryptography

In Quantum Key Distribution (QKD), superposition ensures that any attempt to intercept information disturbs the quantum state, making eavesdropping detectable.

Quantum Sensors and Metrology

Devices like quantum gyroscopes and quantum clocks exploit superposition to achieve extreme precision in measurements.

Quantum gyroscope illustrating superposition-based orientation detection.
Quantum Gyroscope: Demonstrating the role of quantum superposition in precision rotational sensing and orientation stability.

This digital illustration depicts a futuristic quantum gyroscope, utilizing entangled particles and superposition to achieve ultra-precise orientation tracking. The central gyroscopic core hovers in a state of quantum balance, surrounded by glowing trajectories and probability fields that shift as the system evolves. Holographic overlays and grid structures represent quantum phase coherence, interference effects, and entanglement loops used to maintain directional accuracy. This visualization highlights how quantum technologies leverage wavefunction superposition for advanced inertial navigation systems, particularly in aerospace and submarines, where GPS-independent rotation sensing is critical.

A futuristic quantum clock surrounded by wave patterns and probability clouds, illustrating time measurement through quantum superposition.
Quantum Clock: Demonstrating the use of quantum superposition in precision timekeeping, where atomic states evolve in parallel to enhance timing accuracy.

This illustration portrays a conceptual quantum clock that leverages the principle of superposition for ultra-precise timekeeping. The central mechanism is framed by dynamic quantum waves and interference patterns, symbolizing multiple simultaneous atomic states. These overlapping states allow the quantum clock to measure time intervals with remarkable accuracy, surpassing classical atomic clocks. The design integrates quantum coherence and probabilistic phase evolution, crucial for quantum metrology and fundamental physics experiments exploring time at microscopic scales.


Experimental Evidence of Superposition

Quantum superposition is not just theoretical—it has been observed in numerous experiments:

  • Double-Slit Experiment: Particles like electrons and photons exhibit interference patterns when not observed, demonstrating superposition of paths.
A diagram showing quantum interference in the double-slit experiment, with a particle source, two horizontal slits, and an interference pattern forming on a detection screen.
Quantum Interference Pattern from the Double-Slit Experiment
  • Superconducting Circuits: Macroscopic superpositions have been observed in superconducting quantum circuits, where electric currents flow in opposite directions simultaneously.
  • Interference of Large Molecules: Experiments have shown that even large molecules (like buckyballs) can exhibit superposition, suggesting the boundary between quantum and classical behavior is not yet fully understood.

Why Study Quantum Superposition in Quantum Mechanics

Foundation of Quantum Theory

Quantum superposition is one of the most fundamental principles in quantum mechanics. It asserts that a quantum system can exist in multiple states simultaneously until it is measured. This principle challenges classical notions of determinism and reality, and provides a radically different framework for understanding physical systems. Studying this concept is essential to grasping the mathematical and conceptual basis of quantum physics.

Interference and Probability Amplitudes

Superposition allows for interference between quantum states, which leads to outcomes governed by probability amplitudes rather than fixed certainties. These interference effects explain phenomena like diffraction patterns in the double-slit experiment. Understanding how amplitudes combine is critical for predicting the likelihood of measurement outcomes. This makes quantum mechanics both powerful and counterintuitive.

Wave-Particle Duality

Quantum superposition underpins the idea that particles can behave as waves and vice versa. Electrons, photons, and even larger molecules can show wave-like interference patterns when in superposed states. This duality defies classical distinctions and is a defining feature of quantum behavior. Exploring superposition helps students understand how particles exhibit both discrete and continuous properties.

Measurement and Collapse

A key aspect of superposition is that measurement causes a quantum system to collapse into a single observable state. This collapse introduces fundamental questions about the nature of observation and reality. It also plays a central role in quantum paradoxes, such as Schrödinger’s cat. Studying this process leads to a deeper appreciation of the philosophical and technical challenges in quantum theory.

Basis for Quantum Technologies

Superposition is the operational principle behind quantum technologies such as quantum computing, quantum cryptography, and quantum sensors. In a quantum computer, for instance, qubits leverage superposition to perform parallel computations. This opens up new possibilities for solving problems that are intractable for classical computers. Understanding superposition is therefore crucial for anyone interested in the future of quantum engineering and innovation.


Quantum Superposition: Conclusion

The principle of quantum superposition is central to quantum mechanics, revealing that particles can exist in multiple states until observed. It challenges classical notions of reality, causality, and determinism, raising profound philosophical questions about the nature of existence and the role of observation. This principle has been confirmed experimentally and is the foundation for revolutionary technologies like quantum computing, quantum cryptography, and quantum sensing. As research progresses, superposition continues to reshape our understanding of the universe and open doors to technologies once thought impossible. Mathematically, a quantum system is described by a wavefunction (ψ), which encapsulates all possible states the system can be in. If a quantum particle can exist in two distinct states, say ∣A⟩ and ∣B⟩, the superposition principle states that the system can be in a linear combination of these states:

∣Ψ⟩ = α∣A⟩ + β∣B⟩

Where:

∣Ψ⟩ is the superposed state.
α and β are complex probability amplitudes that determine the likelihood of the system being found in state ∣A⟩ or ∣B⟩ when measured.

The probabilities of the system being in state ∣A⟩ or ∣B⟩ are given by ∣α∣² and ∣β∣², respectively, with the condition that ∣α∣² + ∣β∣² = 1.

Quantum Superposition: Review Questions and Answers:

1. What is quantum superposition?
Answer: Quantum superposition is the principle that a quantum system can exist in multiple states simultaneously until measured, at which point the wavefunction collapses to a single state.

2. How is quantum superposition represented mathematically?
Answer: It is represented by a linear combination of basis states in a system’s Hilbert space, where the coefficients (probability amplitudes) determine the likelihood of each state upon measurement.

3. What role does interference play in quantum superposition?
Answer: Interference arises from the combination of probability amplitudes, leading to constructive or destructive effects that shape the probability distribution of outcomes when the system is measured.

4. How does the principle of superposition challenge classical physics?
Answer: Unlike classical objects that exist in a single state, quantum superposition allows particles to be in multiple states at once, fundamentally altering our understanding of reality and measurement at microscopic scales.

5. What is meant by the “collapse” of the wavefunction in the context of superposition?
Answer: Wavefunction collapse refers to the process by which a quantum system in superposition reduces to a single eigenstate upon measurement, yielding a definite outcome.

6. How does superposition contribute to the power of quantum computing?
Answer: In quantum computing, qubits exploit superposition to represent both 0 and 1 simultaneously, allowing parallel computation that can solve complex problems much faster than classical bits.

7. What experimental evidence supports the existence of quantum superposition?
Answer: Experiments such as the double-slit experiment and interference patterns observed with electrons and photons provide strong evidence for superposition, as particles display wave-like behavior and interference effects.

8. How is decoherence related to the loss of superposition in quantum systems?
Answer: Decoherence occurs when a quantum system interacts with its environment, causing the loss of phase relationships between the superposed states, effectively collapsing the system into classical behavior.

9. What is the significance of Schrödinger’s cat thought experiment in explaining superposition?
Answer: Schrödinger’s cat illustrates the paradox of superposition at macroscopic scales, emphasizing the counterintuitive nature of quantum mechanics and the challenges in applying quantum principles to everyday objects.

10. How can quantum superposition be utilized in secure communication systems?
Answer: Superposition underpins quantum cryptography by enabling protocols like quantum key distribution, where the act of measuring a superposed quantum state alters it, alerting communicators to any eavesdropping attempts.

Quantum Superposition: Thought-Provoking Questions and Answers

1. How might the principle of superposition redefine our understanding of reality?
Answer: Quantum superposition challenges the classical view of a single, objective reality by suggesting that particles can exist in multiple states until observed. This raises philosophical questions about the nature of existence and whether reality is fundamentally probabilistic or determined by observation.

2. In what ways could harnessing superposition revolutionize computing and data processing?
Answer: By enabling qubits to be in multiple states simultaneously, superposition allows quantum computers to perform parallel computations on an exponential scale. This could lead to breakthroughs in solving complex problems, optimizing systems, and advancing fields like cryptography and artificial intelligence.

3. How does the concept of superposition influence our interpretation of measurement in quantum mechanics?
Answer: Superposition implies that measurement forces a quantum system to choose one of its many potential states, a process that is inherently probabilistic. This challenges traditional notions of measurement as merely revealing pre-existing conditions and suggests that observation actively shapes reality.

4. Can superposition be observed in macroscopic systems, and what challenges does this present?
Answer: While superposition is well-established in microscopic systems, observing it in macroscopic objects is extremely challenging due to decoherence. Overcoming environmental interactions to maintain superposition in larger systems could pave the way for new technologies but also forces us to reconsider the quantum-classical boundary.

5. How might advances in controlling decoherence enhance the practical applications of superposition in technology?
Answer: Improved methods to isolate quantum systems from environmental noise can prolong coherence times, making superposition more robust. This would enhance the performance of quantum computers and sensors, potentially leading to revolutionary advances in technology and measurement precision.

6. What are the implications of superposition for our understanding of time and causality?
Answer: Superposition implies that particles do not have definite states until measured, which can blur the cause-and-effect relationship in quantum processes. This may lead to new insights into the nature of time and causality, potentially impacting theories of quantum gravity and the flow of time.

7. How might the interplay between superposition and entanglement lead to novel quantum phenomena?
Answer: When combined, superposition and entanglement can produce complex correlations that are not possible classically. This interplay could enable new forms of quantum communication, computing, and simulation, revealing deeper layers of quantum behavior and interconnectivity.

8. In what ways could the study of superposition impact our understanding of consciousness and decision-making?
Answer: Some theories suggest that quantum superposition might play a role in brain processes and consciousness, though this remains highly speculative. Investigating these ideas could provide new perspectives on free will, perception, and the neural basis of decision-making.

9. How does the concept of superposition relate to the multiverse interpretation of quantum mechanics?
Answer: The multiverse interpretation posits that all possible outcomes of quantum measurements occur in separate, non-communicating branches of the universe. Superposition, where multiple states coexist, is seen as evidence that these states may represent parallel realities, challenging our conventional understanding of existence.

10. What experimental techniques are most promising for directly observing superposition in novel systems?
Answer: Techniques such as ultrafast spectroscopy, interference experiments with large molecules, and superconducting qubits are at the forefront of observing superposition in new regimes. These methods push the boundaries of coherence and could help bridge the gap between quantum and classical physics.

11. How might quantum superposition contribute to the development of future energy-efficient technologies?
Answer: Superposition can enable highly efficient quantum algorithms that perform complex calculations with minimal energy consumption. These advancements could lead to new energy-saving technologies in computing and materials science, reducing the overall energy footprint of information processing.

12. What ethical and societal questions are raised by the potential of superposition-based technologies, such as quantum computers?
Answer: The development of quantum technologies poses ethical questions regarding data security, privacy, and the potential for disruptive changes in industry and society. Ensuring equitable access, regulating applications, and addressing the societal impact of these powerful technologies are essential for responsible innovation.

Quantum Superposition: Numerical Problems and Solutions

1. Calculate the energy of a photon with a wavelength of 500 nm using E = hc/λ. (h = 4.1357×10⁻¹⁵ eV·s, c = 3.0×10⁸ m/s)
Solution:
λ = 500 nm = 500×10⁻⁹ m
E = (4.1357×10⁻¹⁵ × 3.0×10⁸) / (500×10⁻⁹)
≈ (1.2407×10⁻⁶ eV·m) / (500×10⁻⁹ m)
≈ 2.4814 eV.

2. Determine the ground state energy of an electron in a one-dimensional infinite potential well of width L = 1.0 nm using E₁ = h²/(8mL²). (m = 9.11×10⁻³¹ kg, h = 6.626×10⁻³⁴ J·s)
Solution:
L = 1.0×10⁻9 m
E₁ = (6.626×10⁻³⁴)² / (8 × 9.11×10⁻³¹ × (1.0×10⁻9)²)
≈ 4.39×10⁻67 / 7.288×10⁻48
≈ 6.02×10⁻20 J
Convert to eV: 6.02×10⁻20 J / 1.602×10⁻19 ≈ 0.376 eV.

3. Compute the de Broglie wavelength of an electron with kinetic energy 50 eV. (Use E = p²/(2m) and λ = h/p)
Solution:
E = 50 eV = 50 × 1.602×10⁻19 J = 8.01×10⁻18 J
p = √(2mE) = √(2 × 9.11×10⁻³¹ × 8.01×10⁻18)
≈ √(1.459×10⁻47) ≈ 1.208×10⁻23 kg·m/s
λ = h/p = 6.626×10⁻34 / 1.208×10⁻23
≈ 5.48×10⁻11 m.

4. Using the uncertainty principle ΔxΔp ≥ h/4π, find the minimum momentum uncertainty Δp if Δx = 1.0×10⁻10 m. (h = 6.626×10⁻34 J·s)
Solution:
Δp ≥ h/(4πΔx) = 6.626×10⁻34 / (4π × 1.0×10⁻10)
≈ 6.626×10⁻34 / 1.2566×10⁻9
≈ 5.27×10⁻25 kg·m/s.

5. Calculate the de Broglie wavelength of an electron moving at 2.0×10⁶ m/s. (m = 9.11×10⁻³¹ kg, h = 6.626×10⁻34 J·s)
Solution:
p = m×v = 9.11×10⁻³¹ × 2.0×10⁶ = 1.822×10⁻24 kg·m/s
λ = h/p = 6.626×10⁻34 / 1.822×10⁻24
≈ 3.637×10⁻10 m.

6. For a hydrogen atom, use the Bohr model to calculate the energy difference (ΔE) between the n=2 and n=1 levels. (E_n = -13.6 eV/n²)
Solution:
E₁ = -13.6 eV, E₂ = -13.6/4 = -3.4 eV
ΔE = E₁ – E₂ = (-13.6) – (-3.4) = -10.2 eV
The energy released is 10.2 eV.

7. Calculate the frequency of a photon with energy 3.0 eV using E = hν. (h = 4.1357×10⁻15 eV·s)
Solution:
ν = E/h = 3.0 eV / 4.1357×10⁻15
≈ 7.25×10¹⁴ Hz.

8. An electron in a hydrogen atom is in an energy state of -1.51 eV (n=3). What is the wavelength of the photon emitted when it transitions to n=2 (E = -3.4 eV)? (ΔE = 1.89 eV, use E = hc/λ with hc = 1240 eV·nm)
Solution:
λ = hc/ΔE = 1240 eV·nm / 1.89 eV
≈ 656 nm.

9. A quantum system has an energy uncertainty ΔE = 0.1 eV. Estimate the minimum lifetime Δt using Δt ≈ ħ/ΔE. (ħ = 6.582×10⁻16 eV·s)
Solution:
Δt = 6.582×10⁻16 / 0.1
≈ 6.582×10⁻15 s.

10. If a photon’s wavelength is measured to be 400 nm, what is its momentum? (p = h/λ, h = 6.626×10⁻34 J·s)
Solution:
λ = 400 nm = 400×10⁻9 m
p = 6.626×10⁻34 / (400×10⁻9)
≈ 1.6565×10⁻27 kg·m/s.

11. Determine the kinetic energy (in eV) of an electron with a momentum of 1.0×10⁻24 kg·m/s. (Use E = p²/(2m), m = 9.11×10⁻31 kg)
Solution:
E = (1.0×10⁻24)² / (2 × 9.11×10⁻31)
= 1.0×10⁻48 / 1.822×10⁻30
≈ 5.49×10⁻19 J
Convert to eV: 5.49×10⁻19 / 1.602×10⁻19
≈ 3.42 eV.

12. A quantum system is confined to a region of size 1.0×10⁻9 m. Estimate the minimum energy uncertainty ΔE using ΔE ≈ ħc/Δx, with ħc ≈ 197 eV·nm.
Solution:
Δx = 1.0×10⁻9 m = 1.0 nm
ΔE ≈ 197 eV·nm / 1.0 nm
= 197 eV.